CARBON AND SOME OF ITS COMPOUNDS.

Allotropy.

By the end of the lesson, the learner should be able to:
Define allotropes and allotropy.
Identify allotropes of carbon.
Represent diamond and graphite diagrammatically.

Teacher exposes new terms.
Review covalent bond.
Discuss boding in diamond and graphite.

text book

K.L.B. BOOK II PP. 131-133

CARBON AND SOME OF ITS COMPOUNDS.

Physical and chemical properties of diamond, graphite and amorphous carbon
Burning carbon and oxygen.
Reduction properties of carbon.
Reaction of carbon with acids. Preparation of CO2.

By the end of the lesson, the learner should be able to:
Describe physical and chemical properties of diamond, graphite and amorphous carbon.
State uses of carbon allotropes.

Discuss physical and chemical properties of diamond, graphite and amorphous carbon.
Explain the Physical and chemical properties of diamond, graphite and amorphous carbon.
Discuss uses of carbon allotropes.

Charcoal, graphite.
Carbon, limewater, tube, limewater stand& Bunsen burner.
CuO, pounded charcoal, Bunsen burner& bottle top
Conc. HNO3, limewater.

K.L.B. BOOK II pp 134

CARBON AND SOME OF ITS COMPOUNDS.

Properties of CO2.
Chemical equations for reactions involving CO2.
Uses of CO2.

By the end of the lesson, the learner should be able to:
Describe properties of CO2

Simple experiments to determine properties of CO2.

Discuss the observations.

Lime water,
Magnesium ribbon,
Universal indicator,
lit candle.
text book

K.L.B. BOOK II PP.138-139

CARBON AND SOME OF ITS COMPOUNDS.

Carbon monoxide lab preparation.
Chemical properties of carbon monoxide.
Carbonates and hydrogen carbonates.
Heating carbonates and hydrogen carbonates.
Extraction of sodium carbonate from trona.

By the end of the lesson, the learner should be able to:
To describe preparation of carbon monoxide in the lab

Teacher demonstration: preparation of carbon monoxide in the lab.
Make observations.

text book

K.L.B. BOOK II PP. 142-143

CARBON AND SOME OF ITS COMPOUNDS.

Solvay process of preparing sodium carbonate.
Importance of carbon in nature. & its effects on the environment.

By the end of the lesson, the learner should be able to:
To draw schematic diagram for extraction of sodium carbonates.

Discuss each step of the process.

Write relevant equations.

text book, chart
text book

K.L.B. BOOK II

NITROGEN AND ITS COMPOUNDS

Introduction to Nitrogen - Properties and Occurrence
Isolation of Nitrogen from Air - Industrial and Laboratory Methods

By the end of the lesson, the learner should be able to:
Describe position of nitrogen in the periodic table
State electron configuration of nitrogen
Identify natural occurrence of nitrogen
Explain why nitrogen exists as diatomic molecules

Teacher exposition: Nitrogen as Group V element, atomic number 7, electron arrangement Discussion: 78% of atmosphere is nitrogen. Q/A: Combined nitrogen in compounds - nitrates, proteins. Explanation: N≡N triple bond strength.

Periodic table charts, Atmospheric composition diagrams, Molecular models showing N≡N triple bond
Aspirator, KOH solution, Copper turnings, Heating apparatus, Fractional distillation flow chart

KLB Secondary Chemistry Form 3, Pages 119

NITROGEN AND ITS COMPOUNDS

Laboratory Preparation of Nitrogen Gas

By the end of the lesson, the learner should be able to:
Prepare nitrogen gas from ammonium compounds
Use sodium nitrite and ammonium chloride method
Test physical and chemical properties of nitrogen
Write equations for nitrogen preparation

Experiment: Mix sodium nitrite (7g) and ammonium chloride ( 5g) with water. Heat gently and collect gas over water. Tests: Color, smell, burning splint, litmus paper, lime water, burning Mg and S. Safety precautions during heating.

Sodium nitrite, Ammonium chloride, Round-bottomed flask, Gas collection apparatus, Test reagents, Deflagrating spoon

KLB Secondary Chemistry Form 3, Pages 121-123

NITROGEN AND ITS COMPOUNDS

Properties and Uses of Nitrogen Gas
Nitrogen(I) Oxide - Preparation and Properties

By the end of the lesson, the learner should be able to:
Describe physical properties of nitrogen
Explain chemical inertness of nitrogen
Describe reactions at high temperatures
List industrial uses of nitrogen

Analysis of test results: Colorless, odorless, does not burn or support combustion. Discussion: Triple bond strength and chemical inertness. High temperature reactions with metals forming nitrides. Uses: Haber process, light bulbs, refrigerant, inert atmosphere.

Property summary charts, Uses of nitrogen displays, Industrial application diagrams
Ammonium nitrate, Test tubes, Gas collection apparatus, Copper turnings, Sulfur, Glowing splints

KLB Secondary Chemistry Form 3, Pages 121-123

NITROGEN AND ITS COMPOUNDS

Nitrogen(II) Oxide - Preparation and Properties
Nitrogen(IV) Oxide - Preparation and Properties

By the end of the lesson, the learner should be able to:
Prepare nitrogen(II) oxide from copper and dilute nitric acid
Observe colorless gas and brown fumes formation
Test reactions with air and iron(II) sulfate
Explain oxidation in air to NO₂

Experiment: Add dilute HNO₃ to copper turnings. Observe brown fumes formation then disappearance. Tests: Effect on litmus, burning splint, FeSO₄ complex formation. Discussion: NO oxidation to NO₂ in air.

Copper turnings, Dilute nitric acid, Gas collection apparatus, Iron(II) sulfate solution, Test reagents
Copper turnings, Concentrated nitric acid, Lead(II) nitrate, Gas collection apparatus, U-tube with ice, Testing materials

KLB Secondary Chemistry Form 3, Pages 125-127

NITROGEN AND ITS COMPOUNDS

Comparison of Nitrogen Oxides and Environmental Effects
Laboratory Preparation of Ammonia

By the end of the lesson, the learner should be able to:
Compare preparation methods of nitrogen oxides
Distinguish between different nitrogen oxides
Explain formation in vehicle engines
Describe environmental pollution effects

Comparative study: Properties table of N₂O, NO, NO₂. Discussion: Formation in internal combustion engines. Environmental effects: Acid rain formation, smog, health problems. Worked examples: Distinguishing tests for each oxide.

Comparison charts, Environmental impact diagrams, Vehicle emission illustrations
Calcium hydroxide, Ammonium chloride, Round-bottomed flask, Calcium oxide, HCl solution, Glass rod, Litmus paper

KLB Secondary Chemistry Form 3, Pages 123-131

NITROGEN AND ITS COMPOUNDS

Preparation of Aqueous Ammonia and Solubility

By the end of the lesson, the learner should be able to:
Prepare aqueous ammonia solution
Demonstrate high solubility using fountain experiment
Explain alkaline properties of aqueous ammonia
Write equations for ammonia in water

Experiment: Dissolve ammonia in water using inverted funnel method. Fountain experiment: Show partial vacuum formation due to high solubility. Tests: Effect on universal indicator, pH measurement. Theory: NH₃ + H₂O equilibrium.

Ammonia generation apparatus, Funnel, Universal indicator, Fountain apparatus, pH meter/paper

KLB Secondary Chemistry Form 3, Pages 134-136

NITROGEN AND ITS COMPOUNDS

Reactions of Aqueous Ammonia with Metal Ions
Chemical Properties of Ammonia - Reactions with Acids and Combustion

By the end of the lesson, the learner should be able to:
Test reactions of aqueous ammonia with various metal ions
Observe precipitate formation and dissolution
Explain complex ion formation
Use reactions for metal ion identification

Experiment: Add aqueous ammonia dropwise to solutions of Ca²⁺, Mg²⁺, Al³⁺, Zn²⁺, Fe²⁺, Fe³⁺, Pb²⁺, Cu²⁺. Record observations with few drops vs excess ammonia. Identify complex ion formation with Zn²⁺ and Cu²⁺.

Various metal salt solutions, Aqueous ammonia, Test tubes, Droppers, Observation recording tables
Various dilute acids, Methyl orange, Oxygen supply, Platinum wire, Copper(II) oxide, Combustion apparatus, U-tube for collection

KLB Secondary Chemistry Form 3, Pages 136-138

NITROGEN AND ITS COMPOUNDS

Industrial Manufacture of Ammonia - The Haber Process
Uses of Ammonia and Introduction to Nitrogenous Fertilizers

By the end of the lesson, the learner should be able to:
Describe raw materials and their sources
Explain optimum conditions for ammonia synthesis
Draw flow diagram of Haber process
Explain economic considerations and catalyst use

Teacher exposition: N₂ from air, H₂ from natural gas/cracking. Process conditions: 500°C, 200 atm, iron catalyst. Flow diagram study: Purification, compression, catalytic chamber, separation, recycling. Economic factors: Compromise between yield and rate.

Haber process flow charts, Industrial diagrams, Catalyst samples, Economic analysis sheets
Fertilizer samples, Percentage calculation worksheets, Use application charts, Calculator

KLB Secondary Chemistry Form 3, Pages 140-141

NITROGEN AND ITS COMPOUNDS

Nitrogenous Fertilizers - Types and Calculations
Laboratory Preparation of Nitric(V) Acid

By the end of the lesson, the learner should be able to:
Calculate percentage nitrogen in various fertilizers
Compare fertilizer effectiveness
Prepare simple nitrogenous fertilizers
Discuss environmental considerations

Worked examples: Calculate % N in (NH₄)₂SO₄, NH₄NO₃, (NH₄)₃PO₄, CO(NH₂)₂, CAN. Comparison: Urea has highest nitrogen content. Practical: Prepare ammonium sulfate from ammonia and sulfuric acid. Environmental impact discussion.

Various fertilizer formulas, Scientific calculators, Laboratory preparation materials, Environmental impact data
Potassium nitrate, Concentrated sulfuric acid, All-glass apparatus, Condenser, Retort stand, Safety equipment

KLB Secondary Chemistry Form 3, Pages 141-144

NITROGEN AND ITS COMPOUNDS

Industrial Manufacture of Nitric(V) Acid

By the end of the lesson, the learner should be able to:
Describe catalytic oxidation process
Explain raw materials and conditions
Draw flow diagram of industrial process
Calculate theoretical yields and efficiency

Teacher exposition: Ostwald process - NH₃ oxidation with Pt-Rh catalyst at 900°C. Flow diagram: Oxidation chamber, cooling, absorption tower. Equations: NH₃ → NO → NO₂ → HNO₃. Economic factors: Catalyst cost, heat recovery.

Industrial process flow charts, Catalyst samples, Process condition charts, Efficiency calculation sheets

KLB Secondary Chemistry Form 3, Pages 145-147

NITROGEN AND ITS COMPOUNDS

Reactions of Dilute Nitric(V) Acid with Metals
Reactions of Dilute Nitric(V) Acid with Carbonates and Hydroxides

By the end of the lesson, the learner should be able to:
Test reactions with various metals
Explain absence of hydrogen gas production
Observe formation of nitrogen oxides
Write equations for metal-acid reactions

Experiment: Add dilute HNO₃ to Mg, Zn, Cu. Test gases produced with burning splint. Observe that no H₂ is produced (except with Mg in very dilute acid). Explain oxidation of any H₂ formed to water. Record observations and write equations.

Various metals (Mg, Zn, Cu), Dilute nitric acid, Test tubes, Gas testing apparatus, Burning splints
Various carbonates and hydroxides, Dilute nitric acid, Lime water, Universal indicator, Test tubes

KLB Secondary Chemistry Form 3, Pages 147-150

NITROGEN AND ITS COMPOUNDS

Reactions of Concentrated Nitric(V) Acid - Oxidizing Properties
Uses of Nitric(V) Acid and Introduction to Nitrates

By the end of the lesson, the learner should be able to:
Demonstrate strong oxidizing properties
Test reactions with FeSO₄, sulfur, and copper
Observe formation of nitrogen dioxide
Explain electron transfer in oxidation

Experiments: (a) Add concentrated HNO₃ to acidified FeSO₄ - observe color change. (b) Add to sulfur - observe reaction. (c) Add to copper turnings - observe vigorous reaction and brown fumes. Explain oxidizing power and reduction to NO₂.

Concentrated nitric acid, Iron(II) sulfate, Sulfur powder, Copper turnings, Test tubes, Fume cupboard access
Industrial use charts, Nitrate salt samples, Preparation method diagrams, Safety data sheets

KLB Secondary Chemistry Form 3, Pages 150-151

NITROGEN AND ITS COMPOUNDS

Action of Heat on Nitrates - Decomposition Patterns

By the end of the lesson, the learner should be able to:
Test thermal decomposition of different nitrates
Classify decomposition patterns based on metal reactivity
Identify products formed on heating
Write equations for decomposition reactions

Experiment: Heat KNO₃, NaNO₃, Zn(NO₃)₂, Cu(NO₃)₂, NH₄NO₃ separately. Test gases with glowing splint. Observe residues. Classification: Group I nitrates → nitrite + O₂; Group II → oxide + NO₂ + O₂; NH₄NO₃ → N₂O + H₂O.

Various nitrate salts, Test tubes, Bunsen burner, Gas collection apparatus, Glowing splints, Observation recording sheets

KLB Secondary Chemistry Form 3, Pages 151-153

NITROGEN AND ITS COMPOUNDS

Test for Nitrates - Brown Ring Test
Environmental Pollution by Nitrogen Compounds

By the end of the lesson, the learner should be able to:
Perform brown ring test for nitrates
Explain mechanism of complex formation
Use alternative copper test method
Apply tests to unknown samples

Experiments: (a) Brown ring test - add FeSO₄ solution to nitrate, then carefully add concentrated H₂SO₄. Observe brown ring formation. (b) Alternative test - warm nitrate with H₂SO₄ and copper turnings. Observe brown fumes. Test unknown samples.

Sodium nitrate, Fresh FeSO₄ solution, Concentrated H₂SO₄, Copper turnings, Test tubes, Unknown nitrate samples
Environmental pollution charts, Acid rain effect photos, Vehicle emission diagrams, Control measure illustrations

KLB Secondary Chemistry Form 3, Pages 153-154

NITROGEN AND ITS COMPOUNDS

Pollution Control and Environmental Solutions
Comprehensive Problem Solving - Nitrogen Chemistry

By the end of the lesson, the learner should be able to:
Analyze methods to reduce nitrogen pollution
Design pollution control strategies
Evaluate effectiveness of current measures
Propose new solutions for environmental protection

Discussion and analysis: Catalytic converters in vehicles, sewage treatment, lime addition to soils/lakes, proper fertilizer application, industrial gas recycling. Group activity: Design pollution control strategy for local area. Evaluation of current measures.

Case studies, Pollution control technology information, Group activity worksheets, Local environmental data
Scientific calculators, Comprehensive problem sets, Industrial data sheets, Experimental result tables

KLB Secondary Chemistry Form 3, Pages 154-157

NITROGEN AND ITS COMPOUNDS

Laboratory Practical Assessment - Nitrogen Compounds
Industrial Applications and Economic Importance

By the end of the lesson, the learner should be able to:
Demonstrate practical skills in nitrogen chemistry
Perform qualitative analysis of nitrogen compounds
Apply safety procedures correctly
Interpret experimental observations accurately

Practical examination: Identify unknown nitrogen compounds using chemical tests. Prepare specified nitrogen compounds. Demonstrate proper laboratory techniques. Safety assessment. Written report on observations and conclusions.

Unknown nitrogen compounds, All laboratory chemicals and apparatus used in chapter, Safety equipment, Assessment rubrics
Economic data sheets, Industry case studies, Agricultural statistics, Cost-benefit analysis templates

KLB Secondary Chemistry Form 3, Pages 119-157

NITROGEN AND ITS COMPOUNDS

Chapter Review and Integration

By the end of the lesson, the learner should be able to:
Synthesize all nitrogen chemistry concepts
Compare preparation methods for nitrogen compounds
Relate structure to properties and reactivity
Connect laboratory and industrial processes

Comprehensive review: Concept mapping of all nitrogen compounds and their relationships. Comparison tables: Preparation methods, properties, uses. Flow chart: Nitrogen cycle in industry and environment. Integration exercises connecting all topics.

Concept mapping materials, Comparison charts, Flow diagram templates, Integration worksheets

KLB Secondary Chemistry Form 3, Pages 119-157

SULPHUR AND ITS COMPOUNDS

Extraction of Sulphur
Allotropes of Sulphur

By the end of the lesson, the learner should be able to:
Define sulphur and state its position in the periodic table. Describe the occurrence of sulphur in nature. Explain the Frasch process for extraction of sulphur. Evaluate the effectiveness of the Frasch process.

Q/A: Review group VI elements and electron configuration of sulphur. Teacher demonstration: Using diagrams to explain the Frasch process setup. Discussion: Why ordinary mining is impossible for sulphur deposits. Group work: Students draw and label the Frasch process diagram.

Charts showing periodic table, Diagram of Frasch process, Samples of sulphur compounds (pyrites, gypsum)
Powdered sulphur, Carbon(IV) sulphide, Evaporating dish, Glass rod, Hand lens, Boiling tubes, Filter paper, Beakers

KLB Secondary Chemistry Form 4, Pages 160-161

SULPHUR AND ITS COMPOUNDS

Physical Properties of Sulphur - Solubility
Physical Properties of Sulphur - Effect of Heat

By the end of the lesson, the learner should be able to:
Investigate the solubility of sulphur in different solvents. Explain the molecular structure of sulphur. Compare solubility in polar and non-polar solvents. State the physical properties of sulphur.

Practical work: Experiment 2(a) - Testing solubility of sulphur in water, benzene, methylbenzene, and carbon(IV) sulphide. Observation and recording in Table Discussion: Explain why sulphur dissolves in organic solvents but not water. Drawing: Puckered ring structure of S8 molecule.

Powdered sulphur, Water, Benzene, Methylbenzene, Carbon(IV) sulphide, Test tubes, Charts showing molecular structure
Powdered sulphur, Test tubes, Bunsen burner, Cold surface for condensation, Thermometer, Safety equipment

KLB Secondary Chemistry Form 4, Pages 163-164

SULPHUR AND ITS COMPOUNDS

Chemical Properties of Sulphur - Reactions with Elements

By the end of the lesson, the learner should be able to:
Investigate the reaction of sulphur with oxygen. Investigate the reaction of sulphur with metals. Write balanced equations for reactions of sulphur. Explain the formation of sulphides.

Practical work: Experiment 3(a) - Burning sulphur in oxygen using deflagrating spoon. Testing with moist litmus paper. Practical work: Heating mixtures of sulphur with iron powder and copper powder. Observation: Exothermic reactions and color changes. Writing equations: Fe + S → FeS, 2Cu + S → Cu2S.

Sulphur, Iron powder, Copper powder, Oxygen gas jar, Deflagrating spoon, Moist litmus papers, Test tubes, Bunsen burner

KLB Secondary Chemistry Form 4, Pages 165-167

SULPHUR AND ITS COMPOUNDS

Chemical Properties of Sulphur - Reactions with Acids
Uses of Sulphur and Introduction to Oxides

By the end of the lesson, the learner should be able to:
Investigate the reaction of sulphur with concentrated acids. Identify the products formed in these reactions. Write balanced equations for oxidation reactions. Test for sulphate ions using barium chloride.

Practical work: Experiment 3(b) - Reactions with concentrated nitric(V) acid, sulphuric(VI) acid, and hydrochloric acid. Testing with barium chloride solution. Observation: Formation of sulphate ions, brown fumes, no reaction with HCl. Discussion: Sulphur as a reducing agent, acids as oxidizing agents.

Sulphur powder, Concentrated HNO3, Concentrated H2SO4, Concentrated HCl, Barium chloride solution, Test tubes, Fume cupboard access
Charts showing uses of sulphur, Samples of vulcanized rubber, Fungicides, Industrial photographs, Textbook diagrams

KLB Secondary Chemistry Form 4, Pages 167-168

SULPHUR AND ITS COMPOUNDS

Preparation of Sulphur(IV) Oxide
Physical and Chemical Properties of Sulphur(IV) Oxide

By the end of the lesson, the learner should be able to:
Describe laboratory preparation of sulphur(IV) oxide. Set up apparatus for gas preparation and collection. Write balanced equations for the preparation reactions. Explain the drying and collection methods used.

Practical work: Experiment 4 - Preparation of SO2 using sodium sulphite and dilute HCl. Apparatus setup: Round-bottomed flask, delivery tube, gas jars. Collection: Downward delivery method. Testing: Using acidified potassium chromate(VI) paper. Alternative method: Copper + concentrated H2SO

Sodium sulphite, Dilute HCl, Round-bottomed flask, Delivery tubes, Gas jars, Concentrated H2SO4 for drying, Acidified potassium chromate(VI) paper
SO2 gas from previous preparation, Litmus papers, Universal indicator, 0.1M NaOH solution, Water, Test tubes, Safety equipment

KLB Secondary Chemistry Form 4, Pages 170-171

SULPHUR AND ITS COMPOUNDS

Bleaching Action of Sulphur(IV) Oxide
Reducing Action of Sulphur(IV) Oxide

By the end of the lesson, the learner should be able to:
Investigate the bleaching properties of SO Compare SO2 bleaching with chlorine bleaching. Explain the mechanism of SO2 bleaching. Relate bleaching to paper manufacturing.

Practical work: Experiment 6 - Placing colored flower petals in SO2 gas. Observation: Temporary bleaching effect. Discussion: SO2 + H2O → H2SO3, reduction of organic dyes. Comparison: Permanent vs temporary bleaching. Application: Paper industry bleaching processes.

Colored flower petals (red/blue), SO2 gas jars, Hand lens for observation, Charts comparing bleaching agents
SO2 gas, Acidified K2Cr2O7, Acidified KMnO4, Bromine water, Iron(III) chloride solution, Concentrated HNO3, Test tubes

KLB Secondary Chemistry Form 4, Pages 173

SULPHUR AND ITS COMPOUNDS

Oxidising Action of Sulphur(IV) Oxide

By the end of the lesson, the learner should be able to:
Investigate SO2 as an oxidizing agent. Demonstrate reaction with stronger reducing agents. Explain the dual nature of SO Write equations for oxidation reactions by SO

Practical work: Experiment 8 - Lowering burning magnesium into SO2 gas. Observation: Continued burning, white fumes of MgO, yellow specks of sulphur. Reaction with hydrogen sulphide gas (demonstration). Discussion: SO2 decomposition providing oxygen. Writing equations: 2Mg + SO2 → 2MgO + S.

SO2 gas jars, Magnesium ribbon, Deflagrating spoon, Hydrogen sulphide gas, Water droppers, Safety equipment

KLB Secondary Chemistry Form 4, Pages 176-177